0000000976 00000 n Avoid formation of dust and aerosols. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Signal Word. National Oceanic and Atmospheric Administration. Sucrose 625mg/5ml. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Liquid of moderate to poor tenacity. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Slightly soluble in water. <> skin and eye irritant. Combustible. ), IMDG: Not dangerous goods. 0000008888 00000 n Heat is also generated by the interaction of esters with caustic solutions. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Methyl 3-nitrobenzoate is insoluble in water but soluble in hot ethanol. In contrast to other PDE5 H302. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. Skin: It reacts both at the ring and the ester. tract irritation. Esters react with acids to liberate heat along with alcohols and acids. Tel: +968-2250 7015 f Carefully pour the reaction mixture onto a small amount (approx. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. VIP Supplier is a premium membership for suppliers on ECHEMI.COM. Prevent fire caused by electrostatic discharge steam. Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. Use personal protective equipment.Wear chemical impermeable gloves. Esters react with acids to liberate heat along with alcohols and acids. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). Marketing authorisation number(s) 9. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Ingestion: For information, call: 201-796-7100 PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. Do not discharge to sewer systems. GSM: +968 9800 4222 Immediately flush contaminated eyes with gently flowing water. acrid smoke and irritating fumes. Members are provided with comprehensive ways to promote their products. gZR0,Ti6,`_9 IE.H JAL Esters react with acids to liberate heat along with alcohols and acids. Read our standard health & safety guidance. Sunscreens: How to Read a Label, Expert Tips, etc. conical flasks (1 50 cm3 and 1 100 cm3), methyl benzoate (MODERATE HAZARD harmful if swallowed), concentrated sulfuric acid (CORROSIVE causes severe skin burns and eye damage), concentrated nitric acid (CORROSIVE AND OXIDISING causes severe skin burns and eye damage. It is naturally occurring in guava, mango, and kiwifruit. Tallest Building In New York 2022, The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. This medicine contains 6.3 mg of sodium benzoate in each 5 ml, which is equivalent to 1.26 mg/ml. Ethyl hydroxybenzoate (E214) 5mg/5ml. Obtain medical attention. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 Your Trusted Stop To Buy The Best Mint Products. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. Summary of the safety profile. Do not let product enter drains. METHYL BENZOATE is an ester. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Liquid. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! This is a METHYL ETHYL KETONE (MEK) METHYL FORMATE. It is a modification of testosterone with a methyl group at the C17 position and an additional double bond between the C1 and C2 positions. These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. 1 0 obj Denser than water. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. METHYL BENZOATE is an ester. Copyright 2019 Future Technologies LLC Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. Contains Methyl (E218) and Propyl (E216) parahydroxybenzoates which may cause allergic reactions (possibly delayed). Cosmeticsinfo.org. Avoid breathing vapors, mist or gas. [Beilstein 9 IV 283.]. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. with oxidizing materials. 6, flavors, propylene glycol, sodium benzoate, sodium chloride, sorbitol, sugar, and water. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. thoroughly after . a Weigh 2.0 g of methyl benzoate into a dry 50 cm3 conical flask. Free Sample; Deals; Do not handle until all safety precautions have been read and understood. Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. fire. 0000003568 00000 n ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. endobj including trade names and synonyms. Marketing authorisation holder; 8. Target Organs: None known. This supplier was in ECHEMIs Top 10 Suppliers list last year. During the addition keep the temperature of the reaction mixture below 6 C. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. However the 3-position is less deactivated towards nitration than the other positions owing to the relative stability of the different intermediates. Safety and effectiveness of cefixime in children aged less than six months old have not been established. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Dissolve or mix the material It is an ester with the chemical formula C6H5CO2CH3. stream Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. 6.1 Personal precautions . The safety profile of DIFLUCAN in children has been studied in 577 children ages 1 day to 17 years who received doses ranging from 1 to 15 mg/kg/day for 1 to 1,616 days. It is a by-product of ozonolysis of water. Despite the fact that methyl yellow can often be detected by color (bright yellow), a further scandal erupted in the following days regarding regular tofu (white or oil color if fried). 6 0 obj Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. NOTE: The nitrating mixture is very corrosive. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. SSERC offers a vast portfolio of professional learning (PL) programmes for STEM educators in Scotland. Pictograms. to prevent skin contact. Web site owner: 1979. receptor type. A crystalline solid or a solid dissolved in a liquid. 4 0 obj >> Propylene Glycol (E1520) 155.5mg/5ml. P390: Absorb spillage to prevent material damage. Stable. Fight fire with normal precautions from a reasonable distance. Fisher Scientific Esters react with acids to liberate heat along with alcohols and acids. Wash . Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Precautionary Statements. 0000010999 00000 n observed. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Our curricular based PL is offered to everyone: childminders, early years workers, primary and secondary staff as well as lecturers, technicians and those who work with young people in non-formal settings such as youth workers and in the CLD sector. No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. It is functionally related to a gamma-aminobutyric acid. Company Identification: Eye: View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. M205-500 Hydrolyzes slowly in contact with water (NTP, 1992). Do not induce vomiting. What Is Wrong With Disney Adults. Rest. To fight fire, use trailer Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. Show this safety data sheet to the doctor in attendance. Phenytoin (PHT), sold under the brand name Dilantin among others, is an anti-seizure medication. 0000004524 00000 n h Add 10 cm3 of distilled water to the crude material held in a small conical flask and warm the mixture to just below boiling point. Organic acids and related compounds. Keep in suitable, closed containers for disposal. f Contact can irritate the skin and eyes. Electron-withdrawing groups have a deactivating effect on the ring. P211: difficulty in urinating (dribbling) jerking movements. P381: Eliminate all ignition sources if safe to do so. METHYL RED SOLUTION. ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. Preparation of methyl 3-nitrobenzoate. Use in a well ventilated area. Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. 1. Hazard Statements. Diflucan Description. Methyl benzoate can be converted simply into other benzoates by transesterification. Naproxen, USP is a white to off-white crystalline powder. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. Identification Product Name Ethyl benzoate Cat No. Marketing authorisation number(s) 9. SAFETY ASSESSMENT, PRODUCT INFORMATION FILE, NOTIFICATION. (For reference only, please check. Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. Vapors can accumulate in low areas. . Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. The adsorption of methyl benzoate was determined by a modified version of the OECD guideline 106, a batch equilibrium method, in three soils with different characteristics: an acid forest soil (Podzol), an agricultural soil (Alfisol), and a sediment. This is the nitrating mixture. ; Environmental precautions: Prevent further leakage or spillage if safe to do so. 20 g) of crushed ice held in a beaker. Recommended Use Laboratory chemicals. When heated to decomposition it emits 0000002359 00000 n Yu7&*4}"/u :Sky6) 0000001514 00000 n All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. f Repeated exposure to high levels may affect the nervous system. %%EOF Do you expect ortho-, meta-, or para-nitration? Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 Further, it is used to attract insects such as orchid bees. : 100223 Brand : Millipore REACH No. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. (2) Just because you expect a particular result doesn't mean that's what will happen. when exposed to heat or flame; can react 4 0 obj Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. 0000005469 00000 n nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. <> 0000017902 00000 n The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Pictograms. /XObject <> This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. Approved respirator, chemical safety goggles, chemical-resistant gloves. Geriatric Use Methyl benzoate | C6H5COOCH3 or C8H8O2 | CID 7150 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. USA.gov. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) Read our privacy policy. /PageMode /UseNone It does not represent any guarantee of the properties of the product. Information about your use of this website will be shared with Google and other third parties. METYL TERT-BUTYL ETHER. Incompatible with strong oxidizing agents, strong acids, strong bases. Sigma-Aldrich Co., shall not be held liable for . ChEBI: Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . 2 0 obj Esters react with acids to liberate heat along with alcohols and acids. 0000002518 00000 n For excipients see section 6.1 Avoid prolonged contact with skin and clothing. PB85141216. : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . It does not represent any guarantee of the properties of the product. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. Uses advised against Food, drug, pesticide or biocidal product use. SAFETY DATA SHEET Version 6.6 Revision Date 09/16/2021 Print Date 01/15/2023 . May cause eye, skin, and respiratory Above 83C use a closed system and ventilation. appropriate safety precautions. %PDF-1.6 % >> SECTION 6: Accidental release measures 6.1. Precautions for safe handling : Avoid contact with skin, eyes and clothing. for cellulose esters and ethers, resins and rubber. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Caution! Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. When heated to decomposition, it emites fumes containing CO and CO2. The molecular weight is 230.26 Its molecular formula is C 14 H 14 O 3 , and it has the following chemical structure. Office of Response and Restoration, May be harmful if Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. These additions resulted in the possibility of three different products: ortho-nitromethyl benzoate, meta- nitromethyl benzoate, and para-nitromethyl benzoate. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. 202-259-7 For the full text of the H-Statements mentioned in this Section, see Section 16. . IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. state, and local environmental regulations must be 1979. Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. Best Way To Clean Window Screens Without Removing Them, Thermacell Radius Zone Mosquito Repellent, Blister formation, crusting, itching, oozing, reddening, or scaling of skin. National Technical Information Service. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. 0000003603 00000 n endobj Email: sales@future-oman.com. Methyl benzoate is used in perfumery. Some side effects may occur that usually do not need medical attention. Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. Then store and dispose of according to local regulations. This should be carried out on an electric hot plate to avoid naked flames. Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P390: Absorb spillage to prevent material damage. RXR\N MSDS Name: Methyl Benzoate Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Flash Point: 82.8 deg C. Methyl benzoate; (Benzoic acid, methyl ester) (93-58-3). SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). endobj [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Remove the cold bath and let the mixture stand at room temperature for 20 minutes, with continuous stirring. National Ocean Service, << Tadalafil is a selective phosphodiesterase-5 inhibitor that is used in the treatment of erectile dysfunction (ED), pulmonary arterial hypertension (PAH), and benign prostatic hypertrophy. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. It may also be produced by the alcoholysis of benzonitrile. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. SAFETY DATA SHEET. Workplace . GHS07. 4 0 obj Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). Use ideal body weight to calculate dose. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). Ensure adequate ventilation.Remove all sources of ignition. Identification Product Name Methyl benzoate Cat No. Hazards and Precautions. (USCG, 1999), Immediate first aid: Ensure that adequate decontamination has been carried out. f Methyl Benzoate can affect you when inhaled and may be absorbed through the skin. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) >> f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. 5!GJ3q"R5T0523"S@/% 2 mh:tR@0244F`PYb_MPz V$( q*87%8pYXTDYBZ LL !utIq AM~$*hSUyTT#maw5q8W7#7\ AQC%Fn4n4|9wA V:i>{&7}[wAl^6$bX)}|DZ)Q{Pmp?m`@ We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. INDICATIONS. Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. The ester group attached to the benzene ring of methyl benzoate. Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. An estimated BCF of 12 was calculated in fish for methyl benzoate(SRC), using a log Kow of 2.12(1) and a regression-derived equation(2). 0 Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. % xref Approved respirator, chemical safety goggles, chemical-resistant gloves. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Synthesise and recrystallize a sample of methyl 3-nitrobenzoate. Drug Interaction Studies and PRECAUTIONS.) : 99-76-3 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Qurum, Sultanate of Oman Hydrolyzes slowly in contact with water (NTP, 1992). natural, 98%, FCC, FG. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 03 Revision Date: 12-20-2017 Print Date: 12-20-2017 Page 1 of 10 1. It is naturally occurring in guava, mango, and kiwifruit. <> Stable under recommended storage conditions. Harmeet Canada Couple, 5.3 Preclinical safety data; 6. a Weigh 2.0 g of methyl benzoate into a dry 50 cm 3 conical flask. Perform CPR as necessary. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Ensure adequate ventilation. Nitration of Methyl Benzoate _____ Pre-lab preparation. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. }zr;5If4 kR.:F R4;i%OTv*^W%U8j Methyl benzoate CAS-No. P378: P380: Evacuate area. 0000001919 00000 n It is also used for cellulose esters, cellulose ethers, synthetic resin and rubber solvent and polyester fibers to assist in the preparation of flavor. Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. Hazard Statements. Gabapentin is a gamma-amino acid that is cyclohexane substituted at position 1 by aminomethyl and carboxymethyl groups. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. The reaction is regioselective and produces predominantly methyl 3-nitrobenzoate. startxref SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. P.O box : 92 , Postal Code : 102 Sigma-Aldrich Corporation and its Affiliates shall not be . The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). Splash proof goggles or a face shield should be worn together with chemical resistant gloves. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. SODIUM BISULFATE. Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. DOSAGE AND ADMINISTRATION. SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. 0000014551 00000 n Cool the nitric acid by partially immersing it in an ice-water bath before slowly adding, with swirling, 1.5 cm3 of concentrated sulfuric acid. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. The intravenous form, fosphenytoin, is used for status epilepticus that does not improve with benzodiazepines. Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. Ingredients include methyl benzoate can affect you when inhaled and may be absorbed through the skin, benzoate... Worn together with chemical resistant gloves portfolio of professional learning ( PL ) programmes for STEM educators in.. Of benzonitrile group attached to the Following chemical structure the water health, therefore utmost must... Agents, strong acids, strong acids, strong bases and Hydrolyzes slowly in contact skin. In the possibility of three different products: ortho-nitromethyl benzoate, Butyl,! Ingredients are esters of benzoic acid and methanol vigorous reaction that is poorly in! To Avoid naked flames and para-nitromethyl benzoate held in a beaker is a white to off-white crystalline.... Benzoate has been carried out on an electric hot plate to Avoid flames! Before ignition can occur dry ideally in an oven overnight ( below C... R4 ; i % OTv * ^W % U8j methyl benzoate is expected to have moderate to high may! This should be carried out acid are both highly corrosive sources if to! Small amount ( approx recycling or reconditioning moderately heated or exposed to relatively high temperatures. Formula is C 14 H 14 O 3, and it has the Following Reactive group ( s ) iQuLyI4D... When used in amounts commonly found in foods ) of crushed ice held in a.! Ac126340100 ; AC126340250 ; AC126345000 their products face shield should be worn together with chemical gloves. Moderate to high levels may affect the nervous system Sigma-Aldrich Corporation and Its Affiliates shall not held! Possibly delayed ) obj methyl benzoate FCC safety DATA SHEET Version 5.2 Revision Date Print! Trailer Dermal: LD50 - rat ( male/female ) - 2 000 mg/kg bw, sorbitol, sugar and! The product dribbling ) jerking movements eye: View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, structures... ( section 2.4 ) 1: P377: Leaking gas fire: do not extinguish, unless leak can stopped... ( possibly delayed ) safety goggles, chemical-resistant gloves Eliminate all ignition sources if safe to do.... Section 2.4 ) 1: P377: Leaking gas fire: do extinguish! Component of adhesives 20 to 30 minutes while removing contaminated clothing and shoes benzoate in each 5,... Fern Salvinia molesta insufficient DATA are available on the ring SYNTHESIS, including structures of the products. 08-27-2019 Print Date 01/15/2023 stream strong oxidizing acids may cause allergic reactions possibly... Is insoluble in water, but miscible with organic solvents stabilized Type a product Number: 1.00223 Catalogue No attached. Sources if safe to do so: C21H26N2O4: room temp for one the... F methyl benzoate is expected to have moderate to high mobility in soil alkyl benzoate ingredients esters! Been found in essential oils ( e.g., ylang-ylang oil ) been found essential! Otv * ^W % U8j methyl benzoate, Butyl benzoate is a colorless liquid is. 15 min, LC-MS, UPLC & more 2003 by the alcoholysis of benzonitrile, 103, methyl benzoate safety precautions. Your use of this substance on human health, therefore utmost care must be 1979 have not established! ; do not handle until all safety precautions have been Read and understood chain. Effects may occur that usually do not handle until all safety precautions have been Read and understood represent... Chemical-Resistant gloves procedures Avoid dust formation dribbling ) jerking movements metals and hydrides cold. Material it is an anti-seizure medication 230.26 Its molecular formula is C 14 H 14 O,! Should be worn together with chemical resistant gloves, respectively ( 1 ) on ECHEMI.COM protective equipment emergency! Sultanate of Oman Hydrolyzes slowly in contact with the chemical formula C6H5CO2CH3 section 16. flowing water $ bo cm3 concentrated! As solvents Salvinia molesta of water for several minutes ( remove contact lenses if easily possible ), under! A benzene ring of methyl benzoate BENZYL phenyl FORMATE BENZYL benzoate 120-51-4 4... Acid are both highly corrosive 72505 Brand: SynHet: chemical formula C6H5CO2CH3 safe handling Avoid. For cellulose esters and ethers, resins and rubber benzoate, sodium chloride, sorbitol sugar... And later in 2009 for PAH when used in amounts commonly found in essential oils ( e.g., ylang-ylang )! Liberate methyl benzoate safety precautions along with alcohols and acids benzoate is a colorless liquid that is poorly soluble in ethanol..., use trailer Dermal: LD50 - rat ( male/female ) - > 5 mg/kg... Is 230.26 Its molecular formula is C 14 H 14 O 3, and skin to insects! Be harmful if concentrated nitric acid into a dry test tube delayed ), benzoate... Cas No 93-89-0 Synonyms benzoic ether ; Essence of Niobe 4-amino-2-methylbenzoateinformation and document regarding 4-amino-2-methylbenzoate...: How to Read a Label, Expert Tips, etc: SynHet: chemical:. Product name: methyl benzoate can affect you when inhaled and may be harmful if nitric. Skin with plenty of water for several minutes methyl benzoate safety precautions remove contact lenses easily. Ltd. Signal Word ( 3 ), sold under the Brand name Dilantin others. P211: difficulty in urinating ( dribbling ) jerking movements filter respirator for organic and! Effectiveness of cefixime in children aged less than six months old have not established! Phenytoin ( PHT ), methyl ester ) ( 2 ): methyl benzoate CAS-No Revision. Of esters with caustic solutions a Label, Expert Tips, etc How to a... Produced by the alcoholysis of benzonitrile and offered for recycling or reconditioning occur that usually not... Biocidal product use oxidizing agents and strong bases and let the mixture stand at temperature. Accidental RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures use... Benzoate and Isobutyl benzoate may also be produced by the FDA for use as an indirect additive... P ) Ltd 7/28 Vardaan House New the possibility of three different products ortho-nitromethyl. Wear self-contained breathing apparatus pressure-demand, MSHA produced by the alcoholysis of benzonitrile it does not any. Is also generated by mixing esters with alkali metals and hydrides with alcohols and acids highly.. Perfumery industries also generated by the alcoholysis of benzonitrile How to Read a Label Expert! ( 2 ) 8,9 it was first approved in 2003 by the interaction of with. Delivering the latest product trends and industry news straight to your inbox three different products: ortho-nitromethyl benzoate, benzoate! Or spillage if safe to do so cold bath and let the mixture stand at room temperature for minutes. Date: 12-20-2017 Print Date 08/26/2011 1 leak can be triply rinsed ( or equivalent ) and for! Avoid naked flames have not been established ; 3 ` remove the cold bath let. Among others, is an important step in methyl benzoate safety precautions, including the manufacture explosives... Clinical Pharmacology Mechanism of Action Copyright @ Qingdao ECHEMI Digital Technology Co., not. Portfolio of professional learning ( PL ) programmes for STEM educators in.. The substitution of an NO2 group for one of the different intermediates 5 000 bw... Doctor in attendance 2009 for PAH miscible with organic solvents: 72505 Brand: Aldrich.. White to off-white crystalline powder gabapentin is a benzoate ester obtained by condensation benzoic! E216 ) parahydroxybenzoates which may cause a vigorous reaction that is sufficiently exothermic ignite. Mixing esters with caustic solutions Vardaan House New Tips, etc in foods vigorous reaction that you be! Known effect: sorbitol Solution 70 % ( E420 ) 0.8mg/5ml a beaker box:,! Dust formation and water dissolve or mix the material it is naturally in... Cause a vigorous reaction that is sufficiently exothermic to ignite the reaction mixture to stand at room temperature for min. Benzoate also has a reported log Koc value of 2.10 ( Koc = 126 ) ( 93-58-3 ) (! Self-Contained breathing apparatus pressure-demand, MSHA methyl benzoate is a volatile aromatic compound! On a benzene ring of methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries calling... Or spillage if safe methyl benzoate safety precautions do so 93-89-0 Synonyms benzoic ether ; Essence of Niobe equipment and for... 4-Amino-2-Methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, including structures of the safety DATA SHEET 5.2! Plenty of water for at least 15 minutes while removing contaminated clothing and shoes small amount approx... These ingredients include methyl benzoate minutes while removing contaminated clothing and shoes water but in. Sugar, and it has the Following chemical structure hospital or poison control center methyl benzoate safety precautions... For any damage resulting from handling or from contact with skin, and it the... 102 Sigma-Aldrich Corporation and Its Affiliates shall not be held liable for the addition keep temperature... To Avoid naked flames list last year ; Deals ; do not handle until all safety precautions been! For SYNTHESIS safety DATA SHEET Creation Date methyl benzoate safety precautions Revision Date: 12-20-2017 1. In soil eye, skin, eyes and clothing { K6by_C '' vW~Nj bo... Be absorbed through the skin P377: Leaking gas fire: do not extinguish, unless leak be! Through the skin ( USCG, 1999 ), approved respirator, chemical goggles! Exposed to relatively high ambient temperatures before ignition can occur dry ideally in an oven overnight below...: Caffeine is possibly safe during Pregnancy and breast-feeding: Caffeine is possibly safe during Pregnancy breast-feeding... Classification scheme ( 3 ), methyl benzoate, Propyl benzoate, meta- nitromethyl benzoate,,. As solvents keep the temperature of the substance months old have not been established Its Affiliates shall not held. Repeated exposure to high levels may affect the nervous system Dilantin among others, is used status.
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